CH3501 Chemical Engineering Thermodynamics II Syllabus:
CH3501 Chemical Engineering Thermodynamics II Syllabus – Anna University Regulation 2021
OBJECTIVE:
The course is aimed to
Understand the phase Behavior of fluids under different PVT conditions and apply them for practical purposes. The course will render a comprehensive understanding of theory and application of solution thermodynamics.
UNIT I SOLUTION THERMODYNAMICS
Partial molar properties, ideal and non-ideal solutions, standard states definition and choice, Gibbs Duhem equation, excess properties of mixtures, pure species and liquids.
UNIT II PHASE EQUILIBRIA
Phase equilibrium in ideal solution, excess Gibbs free energy models, Henry’s law, fugacity, Phase diagrams for homogeneous systems and for systems with a miscibility gap, effect of temperature and pressure on azeotrope composition, liquid-liquid equilibrium, ternary liquid-liquid equilibrium.
UNIT III CORRELATION AND PREDICTION OF PHASE EQUILIBRIA
Vapor-Liquid Equilibrium at low, moderate and high pressures; bubble and dew point calculation, thermodynamic consistency test of VLE data
UNIT IV CHEMICAL REACTION EQUILIBRIA
Chemical Reaction Equilibrium of single and multiple reactions, Standard Gibbs free change, equilibrium constant-effect of temperature; homogeneous gas and liquid phase reactions.
UNIT V REFRIGERATION
Principles of refrigeration, methods of producing refrigeration, liquefaction process, coefficient of performance, Evaluation and performance of vapor compression and gas refrigeration cycles.
TOTAL: 45 PERIODS
OUTCOMES:
On the completion of the course students are expected to
CO1: Understand the systematic development of new class of properties to describe real mixtures
CO2: Develop the idea of chemical potential to derive the idea of phase equilibria
CO3: Understand the relationship connecting T, P and composition originating from the concept of chemical potential and fugacity coefficient
CO4: Understand the principle of chemical reaction thermodynamics for the prediction of equilibrium conversion.
CO5: Analyze the ideal and actual vapor-compression refrigeration cycle and Evaluate the performance of Liquefaction processes
TEXT BOOKS:
1. Smith J.M., Van Ness, H.C., &Abbot M.C,” Introduction to Chemical Engineering thermodynamics”, McGraw Hill VII Edition 2009
2. Kyle B.G.,” Chemical and Process Thermodynamics”, Pearson International third Edition 2015.
3. Rao Y.V.C.,” Chemical Engineering Thermodynamics” Universities Press,2005
REFERENCES
1. Sandler,S.I.,”Chemical and Engineering Thermodynamics”,IV Edition,Wiley,2006.
2. Narayanan K.V”A Text Book of Chemical Engineering Thermodynamics ”Prentice Hall of India Pvt.Ltd,2nd edition,2013