PE3451 Chemical Engineering Thermodynamics Syllabus:
PE3451 Chemical Engineering Thermodynamics Syllabus – Anna University Regulation 2021
COURSE OBJECTIVES:
• To enable the students to learn PVT behaviour of fluids, laws of thermodynamics, thermodynamic property relations and their application to fluid flow, power generation and refrigeration processes.
UNIT I PVT RELATIONS AND FIRST LAW OF THERMODYNAMICS
Scope of thermodynamics, basic concepts and definitions, Equilibrium state and phase rule, Energy, Work, Temperature and Zeroth Law of Thermodynamics, reversible and irreversible process, Ideal gas- Equation of State involving ideal and real gas, Law of corresponding states, Compressibility chart, First Law of Thermodynamics and its consequences.
UNIT II SECOND LAW AND THERMODYNAMIC CORRELATIONS
Application of first Law of Thermodynamics for Flow and non-flow processes. Limitations of the first Law, statements of second Law of Thermodynamics, Thermodynamic Temperature scale, Entropy, Third law of thermodynamics. Thermodynamic Potentials, thermodynamic correlation, Maxwell relations. Clapeyron equation.
UNIT III SOLUTION THERMODYNAMICS
Partial molar properties, ideal and non-ideal solutions, standard states definition and choice, Gibbs-Duhem equation, activity and property change of mixing, excess properties of mixtures. Activity coefficient-composition models.
UNIT IV PHASE EQUILIBRIA
Phase equilibrium in ideal solution, excess Gibbs free energy models, Henry’s law, fugacity, VaporLiquid Equilibrium at low, moderate and high pressures; bubble and dew point calculation, thermodynamic consistency test of VLE data, Phase diagrams for homogeneous systems and for systems with a miscibility gap, effect of temperature and pressure on azeotrope composition, liquid-liquid equilibrium.
UNIT V REACTION EQUILIBRIA
Chemical Reaction Equilibrium of single and multiple reactions, Standard Gibbs free change, equilibrium constant-effect of temperature; homogeneous gas and liquid phase reactions.
TOTAL: 45 PERIODS
COURSE OUTCOMES:
Upon successful completion of the course, the students would be able to
• Understand PVT relations and first law of thermodynamics
• Apply second law and analyse the feasibility of system/devices
• Understand the systematic development of new class of properties to describe real mixtures
• Develop the idea of chemical potential to derive the idea of phase equilibria
• Understand the principle of chemical reaction thermodynamics for the prediction of equilibrium conversion.
TEXT BOOKS:
1. Sonntag, Borgnakke, Van Wylen, Fundamentals of Thermodynamics, 7th Edition, Wiley India, New Delhi, 2009.
2. Narayanan, K.V. A Textbook of Chemical Engineering Thermodynamics Prentice Hall India, 2004
3. Smith, van Ness and Abbott, “Chemical Engineering Thermodynamics”, 7th Edition, McGraw Hill, New York, 2005
REFERENCES:
1. S. I. Sandler, Chemical, Biochemical and Engineering Thermodynamics, Wiley New York, 2006
2. Y V C Rao, “Chemical Engineering Thermodynamics”, Universities Press, Hyderabad 2005.
3. Pradeep Ahuja,” Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).
4. Gopinath Halder,” Introduction to Chemical Engineering Thermodynamics”, PHI Learning Ltd (2009).